Indication of Particular Risks
|
R1:
| Explosive when dry
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2:
| Risk of explosion by shock, friction, fire or other sources of ignition
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3:
| Extreme risk of explosion by shock, friction, fire or other sources of ignition
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4:
| Forms very sensitive explosive metallic compounds
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5:
| Heating may cause an explosion
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6:
| Explosive with or without contact with air
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7:
| May cause fire
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8:
| Contact with combustible material may cause fire
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9:
| Explosive when mixed with combustible material
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10:
| Flammable
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11:
| Highly Flammable
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12:
| Extremely Flammable
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14:
| Reacts violently with water
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15:
| Contact with water liberates extremely flammable gases
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16:
| Explosive when mixed with oxidizing substances
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17:
| Spontaneously flammable in air
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18:
| In use may form flammable/explosive vapor-air mixture
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19:
| May form explosive peroxides
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20:
| Harmful by inhalation
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21:
| Harmful in contact with skin
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22:
| Harmful if swallowed
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23:
| Toxic by inhalation
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24:
| Toxic in contact with skin
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25:
| Toxic if swallowed
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26:
| Very Toxic by inhalation
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27:
| Very Toxic in contact with skin
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28:
| Very Toxic if swallowed
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29:
| Contact with water liberates toxic gas
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30:
| Can become highly flammable in use
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31:
| Contact with acids liberates toxic gas
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32:
| Contact with acids liberates very toxic gas
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33:
| Danger of cumulative effects
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34:
| Causes burns
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35:
| Causes severe burns
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36:
| Irritating to the eyes
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37:
| Irritating to the respiratory system
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38:
| Irritating to the skin
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39:
| Danger of very serious irreversible effects
|
40:
| Limited evidence of a carcinogenic effect
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41:
| Risk of serious damage to eyes
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42:
| May cause sensitization by inhalation
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43:
| May cause sensitization by skin contact
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44:
| Risk of explosion if heated under confinement
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45:
| May cause cancer
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46:
| May cause heritable genetic damage
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48:
| Danger of serious damage to health by prolonged exposure
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49:
| May cause cancer by inhalation
|
50:
| Very Toxic to aquatic organisms
|
51:
| Toxic to aquatic organisms
|
52:
| Harmful to aquatic organisms
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53:
| May cause long-term adverse effects in the aquatic environment
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54:
| Toxic to flora
|
55:
| Toxic to fauna
|
56:
| Toxic to soil organisms
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57:
| Toxic to bees
|
58:
| May cause long-term adverse effects in the environment
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59:
| Dangerous for the ozone layer
|
60:
| May impair fertility
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61:
| May cause harm to the unborn child
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62:
| Possible risk of impaired fertility
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63:
| Possible risk of harm to the unborn child
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64:
| May cause harm to breast-fed babies
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65:
| Harmful: May cause lung damage if swallowed
|
66:
| Repeated exposure may cause skin dryness or cracking
|
67:
| Vapors may cause drowsiness and dizziness
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68:
| Possible risk of irreversible effects
|
|
Combination of Particular Risks
|
R14/15:
| Reacts violently with water, liberating extremely flammable gases
|
5/29:
| Contact with water liberates toxic, extremely flammable gas
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20/21:
| Harmful by inhalation and in contact with skin
|
20/21/22:
| Harmful by inhalation, in contact with skin and if swallowed
|
20/22:
| Harmful by inhalation and if swallowed
|
21/22:
| Harmful in contact with skin and if swallowed
|
23/24:
| Toxic by inhalation and in contact with skin
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23/24/25:
| Toxic by inhalation, in contact with skin and if swallowed
|
23/25:
| Toxic by inhalation and if swallowed
|
24/25:
| Toxic in contact with skin and if swallowed
|
26/27:
| Very Toxic by inhalation and in contact with skin
|
26/27/28:
| Very Toxic by inhalation, in contact with skin and if swallowed
|
26/28:
| Very Toxic by inhalation and if swallowed
|
27/28:
| Very Toxic in contact with skin and if swallowed
|
36/37:
| Irritating to eyes and respiratory system
|
36/37/38:
| Irritating to eyes, respiratory system and skin
|
36/38:
| Irritating to eyes and skin
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37/38:
| Irritating to respiratory system and skin
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39/23:
| Toxic: danger of very serious irreversible effects through inhalation
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39/23/24:
| Toxic: danger of very serious irreversible effects through inhalation in contact with skin
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39/23/24/25:
| Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
|
39/23/25:
| Toxic: danger of very serious irreversible effects through inhalation and if swallowed
|
39/24:
| Toxic: danger of very serious irreversible effects in contact with skin
|
39/24/25:
| Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
|
39/25:
| Toxic: danger of very serious irreversible effects if swallowed
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39/26:
| Very Toxic: danger of very serious irreversible effects through inhalation
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39/26/27:
| Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
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39/26/27/28:
| Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
|
39/26/28:
| Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
|
39/27:
| Very Toxic: danger of very serious irreversible effects in contact with skin
|
39/27/28:
| Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
|
39/28:
| Very Toxic: danger of very serious irreversible effects if swallowed
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42/43:
| May cause sensitization by inhalation and skin contact
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48/20:
| Harmful: danger of serious damage to health by prolonged exposure through inhalation
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48/20/21:
| Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
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48/20/21/22:
| Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
|
48/20/22:
| Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
|
48/21:
| Harmful: danger of serious damage to health by prolonged exposure in contact with skin
|
48/21/22:
| Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
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48/22:
| Harmful: danger of serious damage to health by prolonged exposure if swallowed
|
48/23:
| Toxic: danger of serious damage to health by prolonged exposure through inhalation
|
48/23/24:
| Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
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48/23/24/25:
| Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
|
48/23/25:
| Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
|
48/24:
| Toxic: danger of serious damage to health by prolonged exposure in contact with skin
|
48/24/25:
| Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
|
48/25:
| Toxic: danger of serious damage to health by prolonged exposure if swallowed
|
50/53:
| Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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51/53:
| Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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52/53:
| Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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68/20:
| Harmful: possible risk of irreversible effects through inhalation
|
68/20/21:
| Harmful: possible risk of irreversible effects through inhalation and in contact with skin
|
68/20/21/22:
| Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
|
68/20/22:
| Harmful: possible risk of irreversible effects through inhalation and if swallowed
|
68/22:
| Harmful: possible risk of irreversible effects if swallowed
|
68/21:
| Harmful: possible risk of irreversible effects in contact with skin
|
68/21/22:
| Harmful: possible risk of irreversible effects in contact with skin and if swallowed
|
68/22:
| Harmful: possible risk of irreversible effects if swallowed
|
Safety Phrases
|
Indication of Safety Precautions
|
S1:
| Keep locked up
|
2:
| Keep out of the reach of children
|
3:
| Keep in a cool place
|
4:
| Keep away from living quarters
|
5:
| Keep contents under ... (appropriate liquid to be specified by the manufacturer)
|
6:
| Keep under ... (inert gas to be specified by the manufacturer)
|
7:
| Keep container tightly closed
|
8:
| Keep container dry
|
9:
| Keep container in a well-ventilated place
|
12:
| Do not keep the container sealed
|
13:
| Keep away from food, drink and animal feeding stuffs
|
14:
| Keep away from ... (incompatible materials to be indicated by the manufacturer)
|
15:
| Keep away from heat
|
16:
| Keep away from sources of ignition - No smoking
|
17:
| Keep away from combustible material
|
18:
| Handle and open container with care
|
20:
| When using, do not eat or drink
|
21:
| When using, do not smoke
|
22:
| Do not breathe dust
|
23:
| Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
|
24:
| Avoid contact with skin
|
25:
| Avoid contact with eyes
|
26:
| In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
|
27:
| Take off immediately all contaminated clothing
|
28:
| After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
|
29:
| Do not empty into drains
|
30:
| Never add water to this product
|
33:
| Take precautionary measures against static discharges
|
35:
| This material and its container must be disposed of in a safe way
|
36:
| Wear suitable protective clothing
|
37:
| Wear suitable gloves
|
38:
| In case of insufficient ventilation, wear suitable respiratory equipment
|
39:
| Wear eye/face protection
|
40:
| To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
|
41:
| In case of fire and/or explosion do not breathe fumes
|
42:
| During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
|
43:
| In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
|
45:
| In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
|
46:
| If swallowed, seek medical advice immediately and show this container or label
|
47:
| Keep at temperature not exceeding ... E C (to be specified by the manufacturer)
|
48:
| Keep wetted with ... (appropriate material to be specified by the manufacturer)
|
49:
| Keep only in the original container
|
50:
| Do not mix with ... (to be specified by the manufacturer)
|
51:
| Use only in well-ventilated areas
|
52:
| Not recommended for interior use on large surface areas
|
53:
| Avoid exposure - obtain special instruction before use
|
56:
| Dispose of this material and its container to hazardous or special waste collection point
|
57:
| Use appropriate container to avoid environmental contamination
|
59:
| Refer to manufacturer/supplier for information on recovery/recycling
|
60:
| This material and/or its container must be disposed of as hazardous waste
|
61:
| Avoid release to the environment. Refer to special instructions safety data sheet
|
62:
| If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
|
63:
| In case of accident by inhalation, remove casualty to fresh air and keep at rest
|
64:
| If swallowed, rinse mouth with water (only if the person is conscious)
|
|
|
Combination of Safety Precautions
|
1/2:
| Keep locked up and out of the reach of children
|
3/7:
| Keep container tightly closed in a cool place
|
3/9/14:
| Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
|
3/9/14/49:
| Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
|
3/9/49:
| Keep only in the original container in a cool well-ventilated place
|
3/14:
| Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
|
7/8:
| Keep container tightly closed and dry
|
7/9:
| Keep container tightly closed and in a well-ventilated place
|
7/47:
| Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)
|
20/21:
| When using, do not eat, drink or smoke
|
24/25:
| Avoid contact with skin and eyes
|
27/28:
| After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)
|
29/35:
| Do not empty into drains, dispose of this container and it's material in a safe way
|
29/56:
| Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
|
36/37:
| Wear suitable protective clothing and gloves
|
36/37/39:
| Wear suitable protective clothing, gloves and eye/face protection
|
36/39:
| Wear suitable protective clothing and eye/face protection
|
37/39:
| Wear suitable gloves and eye/face protection
|
47/49:
| Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer
|